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Journal Article

Selective Catalytic Reduction for Treating the NOx Emissions from Lean-Burn Gasoline Engines: Durability Assessment

2008-04-14
2008-01-0811
A laboratory study was performed to assess the potential of using selective catalytic reduction (SCR) with NH3 to treat the NOx emissions from lean-burn gasoline engines. A primary concern was the potential for hot rich exhaust conditions on the vehicle, as such conditions could degrade the zeolite-based SCR catalysts being developed for automotive applications. Samples of an iron/zeolite formulation were aged for 34 hours behind samples of a three-way catalyst (TWC) on a pulse-flame combustion reactor using different A/F ratio schedules that exposed the catalysts to either continuously lean operation, mostly stoichiometric operation, or mostly rich operation. For each A/F ratio schedule, separate SCR samples were aged with inlet temperatures of 750°C, 800°C, or 850°C. The aged SCR samples were evaluated for NOx conversion at 25K hr-1 during lean temperature ramps with 500 ppm NO and NH3.
Journal Article

Detection, Origin and Effect of Ultra-Low Platinum Contamination on Diesel-SCR Catalysts

2008-10-06
2008-01-2488
This paper discusses the poisoning of a selective catalytic reduction (SCR) catalyst by trace levels of platinum originating from an upstream diesel oxidation catalyst (DOC). A diesel aftertreatment system consisting of a DOC, urea based SCR Catalyst and a DPF was aged and evaluated on a 6.4 liter diesel engine dynamometer. The SCR catalyst system consisted of an Fe-zeolite catalyst followed by a Cu-zeolite catalyst. After approximately 400 hours of engine operation at varied exhaust flow rates and temperatures, deactivation of the SCR catalyst was observed. A subsequent detailed investigation revealed that the Cu catalyst was not deactivated and the front half of the Fe-based catalyst showed severe deactivation. The deactivated portion of the catalyst showed high activity of NH3 conversion to NOx and N2O formation. The cause of the deactivation was identified to be the presence of trace Pt contamination.
Journal Article

Fuel Injection Strategies to Improve Emissions and Efficiency of High Compression Ratio Diesel Engines

2008-10-06
2008-01-2472
Simultaneous low NOx (< 0.15 g/kWh) & soot (< 0.01 g/kWh) are attainable for enhanced premixed combustion that may lead to higher levels of hydrocarbons and carbon monoxide emissions as the engine cycles move to low temperature combustion, which is a departure from the ultra low hydrocarbon and carbon monoxide emissions, typical of the high compression ratio diesel engines. As a result, the fuel efficiency of such modes of combustion is also compromised (up to 5%). In this paper, advanced strategies for fuel injection are devised on a modern 4-cylinder common rail diesel engine modified for single cylinder research. Thermal efficiency comparisons are made between the low temperature combustion and the conventional diesel cycles. The fuel injection strategies include single injection with heavy EGR, and early multi-pulse fuel injection under low or medium engine loads respectively.
Journal Article

The Effect of Hydrocarbons on the Selective Catalyzed Reduction of NOx over Low and High Temperature Catalyst Formulations

2008-04-14
2008-01-1030
Selective Catalytic Reduction of NOx is a promising technology to enable diesel engines to meet certification under Tier 2 Bin 5 emissions requirements. SCR catalysts for vehicle use are typically zeolitic materials known to store both hydrocarbons and ammonia. Ammonia storage on the zeolite has a beneficial effect on NOx conversion; hydrocarbons however, compete with ammonia for storage sites and may also block access to the interior of the zeolites where the bulk of the catalytic processes take place. This paper presents the results of laboratory studies utilizing surrogate hydrocarbon species to simulate engine-out exhaust over catalysts formulated to operate in both low (≈175-500°C) and high temperature (≈250-600°C) regimes. The effects of hydrocarbon exposure of these individual species on the SCR reaction are examined and observations are made as to necessary conditions for the recovery of SCR activity.
Journal Article

An Improvement on Low Temperature Combustion in Neat Biodiesel Engine Cycles

2008-06-23
2008-01-1670
Extensive empirical work indicates that the exhaust emission and fuel efficiency of modern common-rail diesel engines characterise strong resilience to biodiesel fuels when the engines are operating in conventional high temperature combustion cycles. However, as the engine cycles approach the low temperature combustion (LTC) mode, which could be implemented by the heavy use of exhaust gas recirculation (EGR) or the homogeneous charge compression ignition (HCCI) type of combustion, the engine performance start to differ between the use of conventional and biodiesel fuels. Therefore, a set of fuel injection strategies were compared empirically under independently controlled EGR, intake boost, and exhaust backpressure in order to improve the neat biodiesel engine cycles.
Journal Article

An Enabling Study of Diesel Low Temperature Combustion via Adaptive Control

2009-04-20
2009-01-0730
Low temperature combustion (LTC), though effective to reduce soot and oxides of nitrogen (NOx) simultaneously from diesel engines, operates in narrowly close to unstable regions. Adaptive control strategies are developed to expand the stable operations and to improve the fuel efficiency that was commonly compromised by LTC. Engine cycle simulations were performed to better design the combustion control models. The research platform consists of an advanced common-rail diesel engine modified for the intensified single cylinder research and a set of embedded real-time (RT) controllers, field programmable gate array (FPGA) devices, and a synchronized personal computer (PC) control and measurement system.
Journal Article

An Advanced and Comprehensive CAE Approach of Piston Dynamics Studies for Piston Optimal and Robust Design

2011-04-12
2011-01-1404
A successful piston design requires eliminate the following failure modes: structure failure, skirt scuffing and piston unusual noise. It also needs to deliver least friction to improve engine fuel economy and performance. Traditional approach of using hardware tests to validate piston design is technically difficult, costly and time consuming. This paper presents an up-front CAE tool and an analytical process that can systematically address these issues in a timely and cost-effectively way. This paper first describes this newly developed CAE process, the 3D virtual modeling and simulation tools used in Ford Motor Company, as well as the piston design factors and boundary conditions. Furthermore, following the definition of the piston design assessment criteria, several piston design studies and applications are discussed, which were used to eliminate skirt scuffing, reduce piston structure dynamic stresses, minimize skirt friction and piston slapping noise.
Journal Article

An Empirical Study to Extend Engine Load in Diesel Low Temperature Combustion

2011-08-30
2011-01-1814
In this work, engine tests were performed to realize EGR-enabled LTC on a single-cylinder common-rail diesel engine with three different compression ratios (17.5, 15 and 13:1). The engine performance was first investigated at 17.5:1 compression ratio to provide baseline results, against which all further testing was referenced. The intake boost and injection pressure were progressively increased to ascertain the limiting load conditions for the compression ratio. To extend the engine load range, the compression ratio was then lowered and EGR sweep tests were again carried out. The strength and homogeneity of the cylinder charge were enhanced by using intake boost up to 3 bar absolute and injection pressure up to 180 MPa. The combustion phasing was locked in a narrow crank angle window (5~10° ATDC), during all the tests.
Journal Article

Motor Vehicle PM Emissions Measurement at LEV III Levels

2011-04-12
2011-01-0623
This paper examines the issues concerning particulate matter (PM) emissions measurement at the 3 mg/mi level proposed as the future LEV III standard. These issues are general in nature, but are exacerbated at the low levels contemplated for upcoming emissions standards. They are discussed in the context of gasoline direct injection (GDI) engines, where they can have an important impact on the continued development of this technology for improved fuel economy. GDI particulate emissions, just as engine-out diesel PM, contain a high fraction of soot. But the total PM mass is significantly lower than from diesel engines, and there can be significant variations in emissions rate and apparent PM composition between cold-start and running emissions. PM emissions levels depend on sampling method and location. As a result, there can be substantial differences in PM sampled and diluted directly at the exhaust pipe, as opposed to measurements from a dilution tunnel.
Journal Article

Test Correlation Framework for Hybrid Electric Vehicle System Model

2011-04-12
2011-01-0881
A hybrid electric vehicle (HEV) system model, which directly simulates vehicle drive cycles with interactions among driver, environment, vehicle hardware and vehicle controls, is a critical CAE tool used through out the product development process to project HEV fuel economy (FE) capabilities. The accuracy of the model is essential and directly influences the HEV hardware designs and technology decisions. This ultimately impacts HEV product content and cost. Therefore, improving HEV system model accuracy and establishing high-level model-test correlation are imperative. This paper presents a Parameter Diagram (P-Diagram) based model-test correlation framework which covers all areas contributing to potential model simulation vs. vehicle test differences. The paper describes each area in detail and the methods of characterizing the influences as well as the correlation metrics.
Journal Article

Fuel Economy and CO2 Emissions of Ethanol-Gasoline Blends in a Turbocharged DI Engine

2013-04-08
2013-01-1321
Engine dynamometer testing was performed comparing E10, E20, and E30 splash-blended fuels in a Ford 3.5L EcoBoost direct injection (DI) turbocharged engine. The engine was tested with compression ratios (CRs) of 10.0:1 (current production) and 11.9:1. In this engine, E20 (96 RON) fuel at 11.9:1 CR gave very similar knock performance to E10 (91 RON) fuel at 10:1 CR. Similarly, E30 (101 RON) fuel at 11.9:1 CR resulted in knock-limited performance equivalent to E20 at 10:1 CR, indicating that E30 could have been run at even higher CR with acceptable knock behavior. The data was used in a vehicle simulation of a 3.5L EcoBoost pickup truck, which showed that the E20 (96 RON) fuel at 11.9:1 CR offers 5% improvement in U.S. EPA Metro-Highway (M/H) and US06 Highway cycle tank-to-wheels CO₂ emissions over the E10 fuel, with comparable volumetric fuel economy (miles per gallon) and range before refueling.
Journal Article

Experimental Evaluation of Advanced Turbocharger Performance on a Light Duty Diesel Engine

2013-04-08
2013-01-0920
For diesel engines to meet current and future emissions levels, the amount of EGR required to reach these levels has increased dramatically. This increased EGR has posed big challenges for conventional turbocharger technology to meet the higher emissions requirements while maintaining or improving other vehicle attributes, to the extent that some OEMs resort to multiple turbocharger configurations. These configurations can include parallel, series sequential, or parallel - series turbocharger systems, which would inevitably run into other issues, such as cost, packaging, and thermal loss, etc. This study, as part of a U.S. Department of Energy (USDoE) sponsored research program, is focused on the experimental evaluation of the emission and performance of a modern diesel engine with an advanced single stage turbocharger.
Technical Paper

Three-Dimensional Simulations of Automotive Catalytic Converter Internal Flow

1991-02-01
910200
The three-dimensional non-reacting flow field inside a typical dual-monolith automotive catalytic converter was simulated using finite difference analysis. The monolithic brick resistance was formulated from the pressure gradient of fully developed laminar duct-flow and corrected for the entrance effect. This correlation was found to agree with experimental pressure drop data, and was introduced as an additional source term into the non-dimensional momentum governing equation within the brick. Flow distribution within the monolith was found to depend strongly on the diffuser performance, which is a complex function of flow Reynolds number, brick resistance, and inlet pipe length and bending angles. A distribution index was formulated to quantify the degree of non-uniformity at selected test cases covering ranges of flow conditions, brick types, and inlet conditions.
Journal Article

Twin-LNT System for Advanced Diesel Exhaust Gas Aftertreatment

2017-03-28
2017-01-0935
The most significant challenge in emission control for compression ignited internal combustion engines is the suppression of NOx. In the US, NOx-levels have faced a progressive reduction for several years, but recently the introduction of the Real Driving Emissions legislation (RDE) in Europe has not only significantly increased the severity of the required emission reduction but now is in the advent of stretching technology to its limits. Emission control is based on engine-internal optimization to reduce the engine-out emissions in conjunction with aftertreatment technologies, that are either Selective Catalytic Reduction (SCR) or Lean NOx Trap (LNT) based systems. Due to its ability to control high amounts of NOx, SCR is widely used in heavy-duty applications and is becoming more popular in light-duty and passenger car applications as well.
Journal Article

A Study of Piston Geometry Effects on Late-Stage Combustion in a Light-Duty Optical Diesel Engine Using Combustion Image Velocimetry

2018-04-03
2018-01-0230
In light-duty direct-injection (DI) diesel engines, combustion chamber geometry influences the complex interactions between swirl and squish flows, spray-wall interactions, as well as late-cycle mixing. Because of these interactions, piston bowl geometry significantly affects fuel efficiency and emissions behavior. However, due to lack of reliable in-cylinder measurements, the mechanisms responsible for piston-induced changes in engine behavior are not well understood. Non-intrusive, in situ optical measurement techniques are necessary to provide a deeper understanding of the piston geometry effect on in-cylinder processes and to assist in the development of predictive engine simulation models. This study compares two substantially different piston bowls with geometries representative of existing technology: a conventional re-entrant bowl and a stepped-lip bowl. Both pistons are tested in a single-cylinder optical diesel engine under identical boundary conditions.
Journal Article

Tier 2 Test Fuel Impact to Tier 3 Aftertreatment Systems and Calibration Countermeasures

2018-04-03
2018-01-0941
During the course of emissions and fuel economy (FE) testing, vehicles that are calibrated to meet Tier 3 emissions requirements currently must demonstrate compliance on Tier 3 E10 fuel while maintaining emissions capability with Tier 2 E0 fuel used for FE label determination. Tier 3 emissions regulations prescribe lower sulfur E10 gasoline blends for the U.S. market. Tier 3 emissions test fuels specified by EPA are required to contain 9.54 volume % ethanol and 8-11 ppm sulfur content. EPA Tier 2 E0 test fuel has no ethanol and has nominal 30 ppm sulfur content. Under Tier 3 rules, Tier 2 E0 test fuel is still used to determine FE. Tier 3 calibrations can have difficulty meeting low Tier 3 emissions targets while testing with Tier 2 E0 fuel. Research has revealed that the primary cause of the high emissions is deactivation of the aftertreatment system due to sulfur accumulation on the catalysts.
Journal Article

Passive Hydrocarbon Trap to Enable SULEV-30 Tailpipe Emissions from a Flex-Fuel Vehicle on E85 Fuel

2018-04-03
2018-01-0944
Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.
Journal Article

TWC+LNT/SCR Systems for Satisfying Tier 2, Bin 2 Emission Standards on Lean-Burn Gasoline Engines

2015-04-14
2015-01-1006
A laboratory study was performed to assess the potential capability of TWC+LNT/SCR systems to satisfy the Tier 2, Bin 2 emission standards for lean-burn gasoline applications. It was assumed that the exhaust system would need a close-coupled (CC) TWC, an underbody (U/B) TWC, and a third U/B LNT/SCR converter to satisfy the emission standards on the FTP and US06 tests while allowing lean operation for improved fuel economy during select driving conditions. Target levels for HC, CO, and NOx during lean/rich cycling were established. Sizing studies were performed to determine the minimum LNT/SCR volume needed to satisfy the NOx target. The ability of the TWC to oxidize the HC during rich operation through steam reforming was crucial for satisfying the HC target.
Journal Article

Passive TWC+SCR Systems for Satisfying Tier 2, Bin 2 Emission Standards on Lean-Burn Gasoline Engines

2015-04-14
2015-01-1004
A laboratory study was performed to assess the potential capability of passive TWC+SCR systems to satisfy the Tier 2, Bin 2 emission standards for lean-burn gasoline applications. In this system, the TWC generates the NH3 for the SCR catalyst from the feedgas NOx during rich operation. Therefore, this approach benefits from high feedgas NOx during rich operation to generate high levels of NH3 quickly and low feedgas NOx during lean operation for a low rate of NH3 consumption. It was assumed that the exhaust system needed to include a close-coupled (CC) TWC, an underbody (U/B) TWC, and an U/B SCR converter to satisfy the emission standards during the FTP and US06 tests while allowing lean operation for improved fuel economy during select driving conditions. Target levels for HC, CO, and NOx during lean/rich cycling were established. With a 30 s lean/10 s rich cycle and 200 ppm NO lean, 1500 ppm NO rich and the equivalent of 3.3 L of SCR volume were required to satisfy the NOx target.
Technical Paper

Ignition Switch Material Definition to Avoid Hard to Start Issue

2020-01-13
2019-36-0138
Nowadays, develop and launch a new product in the market is hard to every company. When we talk about a launch new vehicle to the customers, this task could be considered more difficult than other products whether imagine how fast the technology should be integrated to vehicle. There are main pillars to be considered in this scenario: low cost, design, innovation, competitiveness and safety. Whereas Brazilian economic scenario, all OEM has to be aware to opportunity to make the product profitable and keep acceptable quality. This combination between low cost and quality could be broken or not distributed equally between the pillars. Based on that, in some cases could have a quality broken that will affect directly the customer. This paper will focus on project to define of the new ignition switch, when the main challenge to achieve the cost reduction target was defined to change a material to electrical terminals.
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